Formation and crystal structure of tribarium tetradecaphosphide-ammonia(1/18) Ba3P14 center dot 18NH(3)

Authors
Korber, N Daniels, J
Citation
N. Korber et J. Daniels, Formation and crystal structure of tribarium tetradecaphosphide-ammonia(1/18) Ba3P14 center dot 18NH(3), Z ANORG A C, 625(2), 1999, pp. 189-191
Citations number
8
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
625
Issue
2
Year of publication
1999
Pages
189 - 191
Database
ISI
SICI code
0044-2313(199902)625:2<189:FACSOT>2.0.ZU;2-8
Abstract
Tribarium tetradecaphosphide-ammonia(1/18) Ba3P14. 18NH(3) was prepared by the reduction of red phosphorus with a solution of Ba in liquid NH3. It con tains heptaphosphanortricyclane anions P-7(3-), which are joined via P-Ba c ontacts resulting in (1)(infinity)[Ba-2(P-7)(2)](2-)-chains separated by ba rium octaammine complexes Ba(NH3)(8)(2+).