Tl4Pd3Cl10 - A compound with a new [(PdCl2Cl2/2)(4)](4-) group

Authors
Schupp, B Keller, HL
Citation
B. Schupp et Hl. Keller, Tl4Pd3Cl10 - A compound with a new [(PdCl2Cl2/2)(4)](4-) group, Z ANORG A C, 625(2), 1999, pp. 241-246
Citations number
19
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
625
Issue
2
Year of publication
1999
Pages
241 - 246
Database
ISI
SICI code
0044-2313(199902)625:2<241:T-ACWA>2.0.ZU;2-Y
Abstract
Single crystals of Tl4Pd3Cl10 can be obtained by hydrothermal synthesis. Th ey show tetragonal symmetry with lattice parameters a=15.956(1) Angstrom an d c=14.146(1) Angstrom, Z=8 and space group I (4) over bar 2d (No. 122). Th e atomic arrangement of Tl4Pd3Cl10 is explored by X-ray crystal structure a nalysis. Tl4Pd3Cl10 is the first example of a new structural type with a hi therto not isolated tetramer [(PdCl2Cl2/2)(4)](4-) group.