Synthesis and structural studies of aluminum dialkylamines and dialkylamides: N-chirality of (CH3)(3)AlNHRR ' and cis-trans-isomerism at X2AlNRR ' (X= CH3, Cl, H)

Authors
Dumichen, U
Citation
U. Dumichen, Synthesis and structural studies of aluminum dialkylamines and dialkylamides: N-chirality of (CH3)(3)AlNHRR ' and cis-trans-isomerism at X2AlNRR ' (X= CH3, Cl, H), Z ANORG A C, 625(2), 1999, pp. 262-268
Citations number
27
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
625
Issue
2
Year of publication
1999
Pages
262 - 268
Database
ISI
SICI code
0044-2313(199902)625:2<262:SASSOA>2.0.ZU;2-B
Abstract
Aluminum dialkylamines and dialkylamides were prepared from Al(CH3)(3) and NH(CH3)R' (R': -C2H5, -(C4H9)-C-t) and characterized by elemental analyses, H-1-, C-13-, and Al-27-NMR spectroscopy. The crystal structures of [(CH3)( 2)AlN(CH3) (-(C4H9)-C-t)](2) (IV), [Cl2AlN(CH3)(C2H5)](2) (V), and [H2AlN(C H3)(C2H5)infinity (VI-trans and VI-cis) are discussed.