Chemiluminescence determination of sulfur dioxide in air using tris(1,10-phenanthroline)ruthenium-KIO4 system

Authors
He, ZK Wu, FW Meng, H Yuan, LJ Luo, Q Zeng, YE
Citation
Zk. He et al., Chemiluminescence determination of sulfur dioxide in air using tris(1,10-phenanthroline)ruthenium-KIO4 system, ANAL LETTER, 32(2), 1999, pp. 401-410
Citations number
18
Categorie Soggetti
Chemistry & Analysis","Spectroscopy /Instrumentation/Analytical Sciences
Journal title
ANALYTICAL LETTERS
ISSN journal
00032719 → ACNP
Volume
32
Issue
2
Year of publication
1999
Pages
401 - 410
Database
ISI
SICI code
0003-2719(1999)32:2<401:CDOSDI>2.0.ZU;2-J
Abstract
The emission produced by sulfite in its oxidation by periodate in acidic so lution in the presence of Ru(phen)(3)(2+) is used to determine 1.0x10(-7) t o 1.5x10(-4) mom sulfite. The limit of detection is 7x10(-10) mol/L and the relative standard deviation is 2.3% for a 4x10(-5) mol/L sulfite solution (n=9). The method was applied satisfactorily to the determination of sulfur dioxide in air by using triethanolamine (TEA) as absorbent material.