Bm. Jin et al., MODIFICATION OF UV-VIS OPTICAL-ABSORPTION PROPERTIES CAUSED BY MGO INCORPORATION IN MGO-DOPED LINBO3 CRYSTALS, Materials letters, 30(5-6), 1997, pp. 385-388
MgO-doped LiNbO3 single crystals were investigated in the UV-VIS range
to study the effect of MgO in the LiNbO3 host. Congruent LiNbO3 has a
n optical absorption edge of 3.75 eV. Analysis of the absorption edge
gave an estimate of the indirect band gap for MgO-LiNbO3 solid solutio
ns. The band gap shows an MgO threshold effect in the absorption coeff
icient. An additional indirect transition at 2.2-2.5 eV was revealed w
hen MgO was incorporated into the lithium niobate structure. This indi
rect transition also has a MgO threshold effect around 5 mol% MgO.