General approach to calculating explosion limits for the reaction of hydrogen oxidation

Citation
An. Ivanova et al., General approach to calculating explosion limits for the reaction of hydrogen oxidation, CHEM PHYS R, 17(8), 1998, pp. 1511-1524
Citations number
22
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS REPORTS
ISSN journal
10741550 → ACNP
Volume
17
Issue
8
Year of publication
1998
Pages
1511 - 1524
Database
ISI
SICI code
1074-1550(1998)17:8<1511:GATCEL>2.0.ZU;2-H
Abstract
An analytical formula governing all the three chain-explosion limits inhere nt in hydrogen oxidation is derived using a general approach. The previous equations for the first and second limits derive from this formula as some approximation. The results of calculations by the proposed formula are comp ared with the exact numerical data. The role of nonlinear reaction steps is discussed, and a general concept underlying the analysis of the kinetic be havior in the gap between the second and the third chain explosion limits i s developed.