The study of the electrooxidation of chloride at RuO2/TiO2 electrode usingCV and radiotracer techniques and evaluating by electrochemical kinetic simulation methods

Citation
L. Tomcsanyi et al., The study of the electrooxidation of chloride at RuO2/TiO2 electrode usingCV and radiotracer techniques and evaluating by electrochemical kinetic simulation methods, ELECTR ACT, 44(14), 1999, pp. 2463-2472
Citations number
33
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ELECTROCHIMICA ACTA
ISSN journal
00134686 → ACNP
Volume
44
Issue
14
Year of publication
1999
Pages
2463 - 2472
Database
ISI
SICI code
0013-4686(1999)44:14<2463:TSOTEO>2.0.ZU;2-F
Abstract
The mechanism of the chloride electrooxidation was investigated by CV and r adiotracer techniques, as well as PC simulation methods on RuO2/TiO2 mixed oxide electrodes. The voltammetric behavior of an adsorbed intermediate was studied. Both the experimental and simulation results show that the electrooxidation of chloride is going through the steps of the Volmer-Heyrovsky mechanism o n this working electrode. (C) 1999 Elsevier Science Ltd. All rights reserve d.