An analysis of theoretical knowledge and experimental results of ultraweak
luminescence (UWL) is provided. The role of excited state of molecules and
free radicals, formed in various biochemical reactions, in UWL is discussed
. UWL of model reactions and in vivo systems are compared. The hypothesis o
f coherent electromagnetic field as a source of UWL is also discussed. Spec
tral, kinetic and temporal properties of UWL are summarised, as well as the
ir connection with its origin and role in the organism. Attention is paid t
o recent progress in experimental methods of low-light detection. The possi
ble use of UWL in environmental studies, selection and other applications i
s discussed.