Synthesis and structure of solvent-free hexameric magnesium tri(tert-butyl)silylphosphandiide

Authors
Westerhausen, M Krofta, M Pfitzner, A
Citation
M. Westerhausen et al., Synthesis and structure of solvent-free hexameric magnesium tri(tert-butyl)silylphosphandiide, INORG CHEM, 38(3), 1999, pp. 598
Citations number
17
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
38
Issue
3
Year of publication
1999
Database
ISI
SICI code
0020-1669(19990208)38:3<598:SASOSH>2.0.ZU;2-6
Abstract
Hexameric magnesium tri(terl-butyl)silylphosphandiide crystallizes with a h exagonal Mg6P6 prism and is a rare example of a solvent-free phosphandiide of a hard main group metal. The magnesium atoms show a coordination number of 3 in a trigonal pyramidal surrounding.