T. Yunogami et T. Kumihashi, Sub-quarter-micron Pt etching technology using electron beam resist with round-head, JPN J A P 1, 37(12B), 1998, pp. 6934-6938
Pt patterns of 0.16, 0.25 and 0.36 mu m size and without a sidewall-fence w
ere formed using dipole ring magnetron reactive ion etcher (DRM-RIE) with r
ound-head resist masks of 0.1, 0.2 and 0.28 mu m size written by an electro
n beam. Critical dimension (CD) gains ranged from 50 to 60 nm, and taper an
gles ranged from 72 to 75 degrees. To realize sidewall-fence-free Pt etchin
g with a small CD gain and large taper angle, it is important to tune resis
t selectivity to an optimum. Taper angle becomes small and CD gain becomes
large in the case of low resist selectivity: on the other hand, sidewall-fe
nce is formed in the case of high resist selectivity. Eventually, under the
condition of optimum resist selectivity, no sidewall-fence is formed and t
aper angle and CD gain become large and small, respectively. The optimum re
sist selectivity has been realized under the conditions of low pressure, hi
gh Cl-2 flow rate, and high RF power.