Collective dynamics of random polyampholytes

Citation
Kk. Muller-nedebock et Ta. Vilgis, Collective dynamics of random polyampholytes, J CHEM PHYS, 110(9), 1999, pp. 4651-4657
Citations number
25
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL PHYSICS
ISSN journal
00219606 → ACNP
Volume
110
Issue
9
Year of publication
1999
Pages
4651 - 4657
Database
ISI
SICI code
0021-9606(19990301)110:9<4651:CDORP>2.0.ZU;2-S
Abstract
We consider the Langevin dynamics of a semi-dilute system of chains which a re random polyampholytes of average monomer charge q and with fluctuations in this charge of size Q(-1) and with freely floating counter-ions in the s urrounding. We cast the dynamics into the functional integral formalism and average over the quenched charge distribution in order to compute the dyna mic structure factor and the effective collective potential matrix. The res ults are given for small charge fluctuations. In the limit of finite q we t hen find that the scattering approaches the limit of polyelectrolyte soluti ons. (C) 1999 American Institute of Physics. [S0021-9606(99)52009-6].