Citation
L. Kollar et al., Formation of platinum-tin bond by tin(II)chloride insertion, J CLUST SCI, 9(3), 1998, pp. 321-328
Citations number
38
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF CLUSTER SCIENCE
ISSN journal
10407278
→ ACNP
Volume
9
Issue
3
Year of publication
1998
Pages
321 - 328
Database
ISI
SICI code
1040-7278(199809)9:3<321:FOPBBT>2.0.ZU;2-K
Abstract
The first Sn-119 NMR evidence for the presence of direct platinum-tin bond
in solution has been obtained for PtCl(SnCl3)(bdpp) complex (bdpp = (2S,4S)
-2,4-bis(diphenylphosphino)pentane). Various PtCl2(L-2) complexes (L-2 = he
terobidentate P-P, P-O, P-N, P-S chelating ligands) have been reacted with
tin(II)chloride resulting in the formation of the corresponding PtCl(SnCl3)
(L-2) derivatives. Tin(II)chloride has been inserted into the Pt-Cl bond tr
ans to the harder donor atom of the L-2 ligand.