A new growth technique of CdZnTe single crystals for room-temperature radia
tion detectors is developed. It is based on a free growth from the vapour p
hase on a oriented single crystal seed. Binary polycrystalline CdTe and ZnT
e compounds are placed and heated separately to produce divided Rows which
were introduced into the crystal growth zone where they mixed before deposi
tion on the seed. Monocrystalline and homogeneous materials with high elect
rical resistivity, lour defect density, and crystal volume up to similar to
50 cm(3) are prepared by this technique. (C) 1999 Elsevier Science B.V. Al
l rights reserved.