Three-dimensional arrays of a few nanometer size clusters have been realize
d using a porous silicon (PS) matrix by filling its pores with CdSe or ZnSe
. From the photoluminescence behavior it is concluded that the average size
of the CdSe, ZnSe clusters is about 3-5 nm. We compare the Pt, and Raman s
cattering spectra of the pure PS area of samples with those obtained from t
he embedded areas on the same wafer. The results are consistent with the st
abilization of the PL peak in the case of CdSe in spite of the different PL
peak positions of the pure PS. Pt, spectra of the PS were examined as func
tion of laser irradiation time and laser intensities. (C) 1999 Elsevier Sci
ence B.V. All rights reserved.