Annealing effects on phase transformation and powder microstructure of nanocrystalline zirconia polymorphs

Nanocrystalline zirconia powders in pure form and doped with yttria and cal cia were prepared by the precipitation method. In the as-prepared condition , all the doped samples show only monoclinic phase, independent of the dopa nts and dopant concentration. On annealing the powders at 400 degrees C and above, in the case of 3 and 6 mol% Y2O3 stabilized ZrO2 (3YSZ and 6YSZ), t he monoclinic phase transforms to tetragonal and cubic phases, respectively , whereas in 3 and 6 mol% CaO stabilized ZrO2 (3CSZ and 6CSZ), the volume p ercentage of the monoclinic phase gradually decreases up to the annealing t emperature of about 1000 degrees C and then increases for higher annealing temperatures. The presence of monoclinic phase in the as-prepared samples o f doped zirconia has been attributed to the lattice strain effect which res ults in the less symmetric lattice. For the annealing temperatures below 10 00 degrees C, the phenomenon of partial stabilization of the tetragonal pha se in 3CSZ and 6CSZ can be explained in terms of the grain size effect. Hig h resolution transmission electron microscopy (HRTEM) observations reveal t he lattice strain structure in the as-prepared materials. The particles are found to be a tightly bound aggregate of small crystallites with average s ize of 10 nm. The morphology of the particles is observed to be dependent o n the dopants and dopant concentration.