Gas-sensing properties of a novel surface functionalized tin oxide material
have been studied to demonstrate the possibility of selectivity control by
surface state formation. Covalent anchoring of ruthenium oxide on the tin
oxide surface (ruthenated tin oxide) is found to give considerable enhancem
ent in sensitivity (320) as well as selectivity to 1000 ppm of liquified pe
troleum gas (LPG) at 300 degrees C compared to the sensitivity (4) of pure
tin oxide samples. The amount and distribution of grafted ruthenium oxide o
n the surface of tin oxide seems to be the most important parameter control
ling the change in electrical transport with LPG gas adsorption.