Deviations from ionization equilibrium in the near-cathode region of a high
-pressure high-current are are analysed. Estimates and numerical calculatio
ns are given for an atmospheric-pressure argon are. It is found that the de
viations extend over the distance of about 100 mu m from the cathode surfac
e and are caused by ambipolar diffusion; convective transport of the charge
d particles, barodiffusion, thermal diffusion, diffusion caused by thermal
non-equilibrium between electrons and heavy particles, and transport due to
the presence of the electric current are minor effects.