An unprecedented kappa N-2,H bonding mode for a hydridotris(pyrazolyl)-borato ligand

Authors
Malbosc, F Kalck, P Daran, JC Etienne, M
Citation
F. Malbosc et al., An unprecedented kappa N-2,H bonding mode for a hydridotris(pyrazolyl)-borato ligand, J CHEM S DA, (3), 1999, pp. 271-272
Citations number
17
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
03009246 → ACNP
Issue
3
Year of publication
1999
Pages
271 - 272
Database
ISI
SICI code
0300-9246(19990207):3<271:AUKNBM>2.0.ZU;2-W
Abstract
An unprecedented kappa(2)N,H bonding mode for hydridotris(pyrazolyl)borato (Tp(Me2,4-Cl)) ligand is observed in [Rh(CO)(PMePh2)(2)(Tp(Me2,4-Cl))]; the complex, which features two dangling pyrazole rings and a B-(mu-H)-Rh agos tic bond, is highly fluxional in solution.