Citation
Gb. Deacon et al., Synthesis and structures of photodecarbonylated ruthenium(II) complexes - potential intermediates for mixed ligand complexes, J CHEM S DA, (3), 1999, pp. 275-277
Citations number
17
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
03009246
→ ACNP
Issue
3
Year of publication
1999
Pages
275 - 277
Database
ISI
SICI code
0300-9246(19990207):3<275:SASOPR>2.0.ZU;2-U
Abstract
Irradiation of solutions containing complexes of the type [RuL(CO)(2)Cl-2]
where L is a 2,2'-bipyridine analogue leads to monodecarbonylation and the
formation of dimeric ruthenium(II) complexes, [RuL(CO)(2)Cl](2), for which
two different structures have been established, viz. with a hans dispositio
n of bridging and terminal chlorides [L = di(2-pyridyl) ketone] or with CO
tl ans to bridging chlorides (L = 1,10-phenanthroline).