Paramagnetic centers were studied in different SiOx:N,H films deposited by
plasma-enhanced chemical vapor deposition in a wide composition range. The
total dangling-bond concentration is detected to be proportional to the oxy
gen content. Moreover, sample irradiation by ultraviolet light revealed als
o that nitrogen impurities play some role. In particular, the presence of N
-H bonds induces a release of the him stress, which seems to be related to
the concentration of dangling bonds. It is also shown that both weak Si-Si
and Si-H bonds may serve as precursors for the dangling-bond formation. (C)
1999 American Vacuum Society. [S0734-211X(99)02301-X].