Dielectric criteria for the electrorheological effect

Citation
T. Hao et al., Dielectric criteria for the electrorheological effect, LANGMUIR, 15(4), 1999, pp. 918-921
Citations number
23
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
LANGMUIR
ISSN journal
07437463 → ACNP
Volume
15
Issue
4
Year of publication
1999
Pages
918 - 921
Database
ISI
SICI code
0743-7463(19990216)15:4<918:DCFTEE>2.0.ZU;2-R
Abstract
The suspended particles of an electrorheological (ER) fluid can be easily a rrayed as a crystallite of a body-centered tetragonal (bct) lattice structu re using an external electric field. Thus the entropy of this process, whic h is generally recognized as a first-order phase transition, would greatly decrease. From this fact, we theoretically derive that the dielectric loss tangent maximum value of the dispersed particles should be larger than 0.1, which agrees well with the currently observed experimental results; the ne gative ER effect becomes possible only when d is an element of(sp)/dT < 0, where is an element of(sp) is the static dielectric constant of the dispers ed particle material and T is temperature.