Dielectric criteria for the electrorheological effect
Citation
T. Hao et al., Dielectric criteria for the electrorheological effect, LANGMUIR, 15(4), 1999, pp. 918-921
Categorie Soggetti
Physical Chemistry/Chemical Physics
SICI code
0743-7463(19990216)15:4<918:DCFTEE>2.0.ZU;2-R
Abstract
The suspended particles of an electrorheological (ER) fluid can be easily a
rrayed as a crystallite of a body-centered tetragonal (bct) lattice structu
re using an external electric field. Thus the entropy of this process, whic
h is generally recognized as a first-order phase transition, would greatly
decrease. From this fact, we theoretically derive that the dielectric loss
tangent maximum value of the dispersed particles should be larger than 0.1,
which agrees well with the currently observed experimental results; the ne
gative ER effect becomes possible only when d is an element of(sp)/dT < 0,
where is an element of(sp) is the static dielectric constant of the dispers
ed particle material and T is temperature.