Synthesis and structure 3,5-bis[(2-dimethylamino)phenyl]-2,2,4,4,6,6-hexamethyl-2,4,6-trisilaheptane and 3,6-bis[(2-dimethylamino)phenyl]-2,2,4,4,5,5,7,7-octamethyl-2,4,5,7-tetrasilaoctane

Authors
Mehring, M Jurkschat, K Schurmann, M
Citation
M. Mehring et al., Synthesis and structure 3,5-bis[(2-dimethylamino)phenyl]-2,2,4,4,6,6-hexamethyl-2,4,6-trisilaheptane and 3,6-bis[(2-dimethylamino)phenyl]-2,2,4,4,5,5,7,7-octamethyl-2,4,5,7-tetrasilaoctane, MAIN GR MET, 22(1), 1999, pp. 15-18
Citations number
22
Categorie Soggetti
Chemistry
Journal title
MAIN GROUP METAL CHEMISTRY
ISSN journal
07921241 → ACNP
Volume
22
Issue
1
Year of publication
1999
Pages
15 - 18
Database
ISI
SICI code
0792-1241(199901)22:1<15:SAS3>2.0.ZU;2-P
Abstract
The title compounds [(2-Me2N)C6H4(Me3Si)CH](2)SiMe2 (1) and {[(2-Me2N)C6H4( Me3Si)CH]SiMe2}(2) (2) are examples of new sterically crowd ed tetraorganos ilanes and, respectively. compouds contain two dimethylamino substituted ar omatic rings as potential donor groups bonded to the carbon and silicon con taining chains. However, there is no evidence for intra- or intermolecular N-Si interaction in solution or solid state. No extra symmetry was found fo r molecule 1 whereas molecule 2 lies about a center of inversion.