ELECTRON-SPIN-RESONANCE OF THE H-NH2 RADICAL PAIR

Authors
VANZEE RJ WILLIAMS AP WELTNER W
Citation
Rj. Vanzee et al., ELECTRON-SPIN-RESONANCE OF THE H-NH2 RADICAL PAIR, The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 101(16), 1997, pp. 2917-2920
Citations number
15
Categorie Soggetti
Chemistry Physical
Journal title
The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory → ACNP
ISSN journal
10895639
Volume
101
Issue
16
Year of publication
1997
Pages
2917 - 2920
Database
ISI
SICI code
1089-5639(1997)101:16<2917:EOTHRP>2.0.ZU;2-N
Abstract
Exchange within the radical pairs H ... NH2 and D ... ND2 trapped in s olid argon and krypton at 4 K was observed via electron spin resonance . They were produced from ammonia by radiation from a corona discharge through the rare gas. From the zero-field splittings of the triplet s pecies, it is concluded that the H atom and NH2 are separated by one r are-gas atom in each of these matrices.