T. Keyes, INSTANTANEOUS NORMAL-MODE APPROACH TO LIQUID-STATE DYNAMICS, The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 101(16), 1997, pp. 2921-2930
The instantaneous normal mode (INM) approach to liquid state dynamics
is presented. INM is put in historical context, and the underlying phy
sical ideas, including the importance of the potential energy landscap
e, are explained. It is shown that INM can be the basis of a general s
tarting point for dynamical calculations in liquids, and the theoretic
al developments necessary for future development are indicated. New re
sults are given for the general INM formalism, as well as for depolari
zed light scattering, the ''Boson peak'' in supercooled liquids, frict
ion on a vibrating bond, nonadiabatic solvent induced transitions of a
quantum system coupled to a liquid, and diffusion in supercooled liqu
ids.