INSTANTANEOUS NORMAL-MODE APPROACH TO LIQUID-STATE DYNAMICS

Authors
Citation
T. Keyes, INSTANTANEOUS NORMAL-MODE APPROACH TO LIQUID-STATE DYNAMICS, The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 101(16), 1997, pp. 2921-2930
Citations number
86
Categorie Soggetti
Chemistry Physical
ISSN journal
10895639
Volume
101
Issue
16
Year of publication
1997
Pages
2921 - 2930
Database
ISI
SICI code
1089-5639(1997)101:16<2921:INATLD>2.0.ZU;2-D
Abstract
The instantaneous normal mode (INM) approach to liquid state dynamics is presented. INM is put in historical context, and the underlying phy sical ideas, including the importance of the potential energy landscap e, are explained. It is shown that INM can be the basis of a general s tarting point for dynamical calculations in liquids, and the theoretic al developments necessary for future development are indicated. New re sults are given for the general INM formalism, as well as for depolari zed light scattering, the ''Boson peak'' in supercooled liquids, frict ion on a vibrating bond, nonadiabatic solvent induced transitions of a quantum system coupled to a liquid, and diffusion in supercooled liqu ids.