This paper describes the establishment of a high-accuracy, infrared, spectr
al responsivity scale in the 8 mu m to 12 mu m atmospheric window through t
he calibration of specially designed HgCdTe/sphere detectors. The scale has
been established using intensity-stabilized laser radiation from a grating
-tuned CO2 laser directly with the primary standard cryogenic radiometer of
the UK National Physical Laboratory (NPL). The factor-of-10 improvement in
the uncertainty over the NPL's previous spectral responsivity scale in thi
s spectral region has been achieved mainly through the use of improved tran
sfer standard detectors and the direct calibration of these detectors again
st the cryogenic radiometer. This paper describes these new transfer standa
rds, the intensity-stabilized CO2 laser facility, its use with the NPL cryo
genic radiometer and the improved methodology.