Fast relaxational dynamics in the o-terphenyl glass

Citation
G. Monaco et al., Fast relaxational dynamics in the o-terphenyl glass, PHYS REV L, 82(8), 1999, pp. 1776-1779
Citations number
18
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW LETTERS
ISSN journal
00319007 → ACNP
Volume
82
Issue
8
Year of publication
1999
Pages
1776 - 1779
Database
ISI
SICI code
0031-9007(19990222)82:8<1776:FRDITO>2.0.ZU;2-X
Abstract
The dynamic structure factor S(q, omega) of o-terphenyl, obtained by Brillo uin light scattering (q approximate to 0.04 nm(-1)) in the 1 to 30 GHz rang e, shows signatures of relaxation phenomena at temperatures well within the glassy phase. Using a phenomenological ansatz for the density fluctuations memory function and S(q, omega) data obtained by inelastic x-ray scatterin g at high momentum transfer (q = 1-6 nm(-1)), we describe this relaxational dynamics in terms of two distinct processes: (i) one in the 10(-11) s rang e and slightly temperature dependent, and (ii) an "instantaneous" one, repr esenting the microscopic transient and giving rise to a T-independent contr ibution to the Brillouin linewidth.