Magnetic field acceleration of the ortho-para H-2 conversion on transitionoxides

Citation
E. Ilisca et S. Paris, Magnetic field acceleration of the ortho-para H-2 conversion on transitionoxides, PHYS REV L, 82(8), 1999, pp. 1788-1791
Citations number
18
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW LETTERS
ISSN journal
00319007 → ACNP
Volume
82
Issue
8
Year of publication
1999
Pages
1788 - 1791
Database
ISI
SICI code
0031-9007(19990222)82:8<1788:MFAOTO>2.0.ZU;2-5
Abstract
A new electron-nucleus resonant mechanism is shown to increase the ortho-pa ra conversion rate of hydrogen molecules adsorbed on transition metal oxide s. This mechanism is suggested to interpret the observed conversion rate ac celerations by an external magnetic field and similar effects in a variety of chemical reactions. Since the resonances occur for stringent relations b etween catalyst and molecular parameters, the magnetic field acceleration i s very sensitive to catalyst pretreatments and constitutes a valuable tool to improve the catalytic rates.