Dehydration and dehydrogenation of cyclohexanol over AIPO(4)-5 based molecular sieves

Authors
Nur, H Hamdan, H
Citation
H. Nur et H. Hamdan, Dehydration and dehydrogenation of cyclohexanol over AIPO(4)-5 based molecular sieves, REACT KIN C, 66(1), 1999, pp. 33-38
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
REACTION KINETICS AND CATALYSIS LETTERS
ISSN journal
01331736 → ACNP
Volume
66
Issue
1
Year of publication
1999
Pages
33 - 38
Database
ISI
SICI code
0133-1736(199901)66:1<33:DADOCO>2.0.ZU;2-3
Abstract
The role of incorporated divalent metal (Mn, Mg, Co and Zn) incorporated in to the framework of AlPO4-5 in conversion of cyclohexanol has been examined . The influence of these metals to cyclohexene and cyclohexanone selectivit ies was correlated to the acidity and basicity properties of these molecula r sieves. Possible mechanism for the dehydration and dehydrogenation for cy clohexanol was proposed.