Thermogalvanic effects in dissolution of an nonisothermic iron plate in acid media with various pH values

Citation
Sa. Kaluzhina et al., Thermogalvanic effects in dissolution of an nonisothermic iron plate in acid media with various pH values, RUSS J ELEC, 35(1), 1999, pp. 47-51
Citations number
12
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
ISSN journal
10231935 → ACNP
Volume
35
Issue
1
Year of publication
1999
Pages
47 - 51
Database
ISI
SICI code
1023-1935(199901)35:1<47:TEIDOA>2.0.ZU;2-U
Abstract
A current distribution is studied along an iron plate with a tangential tem perature gradient in the course of its dissolution in acid sulfate media of various pH. The satisfactory correlation between experimental and theoreti cal data proves that models can be designed on the basis of electrochemical kinetics. Employing computer methods, the models may quantitatively predic t thermogalvanic effects in systems under study, where effect of pH appears to be commensurate with the thermal effect.