Mechanism of the interaction of color reagent 1,3-N, N '-bis-4-(4 '-nitro benzenediazo) phenyl squaraine with oxoacid anions

Authors
Yang, ML Sun, ZM Yan, GS
Citation
Ml. Yang et al., Mechanism of the interaction of color reagent 1,3-N, N '-bis-4-(4 '-nitro benzenediazo) phenyl squaraine with oxoacid anions, SCI CHINA B, 42(1), 1999, pp. 70-76
Citations number
14
Categorie Soggetti
Chemistry
Journal title
SCIENCE IN CHINA SERIES B-CHEMISTRY
ISSN journal
1001652X → ACNP
Volume
42
Issue
1
Year of publication
1999
Pages
70 - 76
Database
ISI
SICI code
1001-652X(199902)42:1<70:MOTIOC>2.0.ZU;2-2
Abstract
By AM1 method, the interactions between 1, 3-N, N'-Bis-4-(4'-nitro benzened iazo) phenyl squaraine (BNBPS) and several oxoacid anions have been studied on the basis of the proposed model. The mechanism of the color reactions i s suggested and the answers to the question of whether or not BNBPS colorat es with HCO3-, CO32-, NO2 - , NO3 - , etc. are given. It is theoretically p redicted that BNBPS might be used as the color reagent for SO42-.