Fourier-transform infrared and Raman spectra of glutarimide

Authors
Leroux, N Zeegers-Huyskens, T
Citation
N. Leroux et T. Zeegers-huyskens, Fourier-transform infrared and Raman spectra of glutarimide, SPECT LETT, 32(1), 1999, pp. 47-56
Citations number
11
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
SPECTROSCOPY LETTERS
ISSN journal
00387010 → ACNP
Volume
32
Issue
1
Year of publication
1999
Pages
47 - 56
Database
ISI
SICI code
0038-7010(1999)32:1<47:FIARSO>2.0.ZU;2-W
Abstract
The FT-IR ( from 50 to - 180 degrees C) and the FT-Raman spectra at 25 degr ees C of glutarimide in iu the solid state are investigated. The data are c ompared with recent results of Bienko et al.( J.Phys.Chem.A 101,7834 (1997) on glutarimide isolated in a low-temperature argon matrix. The vibrational changes induced by hydrogen bond formation in the crystalline state are di scussed. The v(NH...O) vibration is observed at 3189 cm(-1) at 25 degrees C and at 3163 cm(-1) at - 180 degrees C. These values correspond to a contra ction of the N...O distance of 0.022 Angstrom.