We have used the low energy electron microscope (LEEM) to investigate step
faceting and striped phase formation on heavily boron-doped Si(001) surface
s. Measurements of thermal fluctuations along the steps, equilibrium island
shapes, and the angle of triangular facets provide quantitative informatio
n on the step formation energies. We find that a simple, systematic tempera
ture dependence of the spatial anisotropy of the free energy of isolated st
eps is sufficient to account for the observed faceting of the B type steps.
These results suggest that the proliferation of straight A step edges at l
ower temperature is caused by the energy of isolated A steps becoming vanis
hingly small. We show that rapid cooling of the samples leads to the nuclea
tion and growth of a high density of vacancy islands on the surfaces. Based
on these results, we propose a qualitative model for mass transport during
stripe formation.