Rapid synthesis of diaryl carbazone by N-Bromosuccinimide and pyridine as the oxidation system

Citation
Yl. Wang et al., Rapid synthesis of diaryl carbazone by N-Bromosuccinimide and pyridine as the oxidation system, SYN COMMUN, 29(3), 1999, pp. 423-428
Citations number
8
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
29
Issue
3
Year of publication
1999
Pages
423 - 428
Database
ISI
SICI code
0039-7911(1999)29:3<423:RSODCB>2.0.ZU;2-K
Abstract
A new and rapid synthetic method of diaryl carbazone (ArN=NCONHNHAr) from a ryl substituted carbazide is reported for the first time. Eight of the comp ounds were prepared by oxidation of aryl substituted carbazide using N-Brom osuccinimide and pyridine as the oxidation system in good yield under mild condition. This method only need simple instrument and short reaction time. A possible mechanism is suggested.