Indirect electrochemical reductive degradation of polycarbonates

Authors
Pud, AA Rogalsky, SP Shapoval, GS Voloshchuk, VG
Citation
Aa. Pud et al., Indirect electrochemical reductive degradation of polycarbonates, TEOR EKSP K, 34(5), 1998, pp. 319-323
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
TEORETICHESKAYA I EKSPERIMENTALNAYA KHIMIYA
ISSN journal
04972627 → ACNP
Volume
34
Issue
5
Year of publication
1998
Pages
319 - 323
Database
ISI
SICI code
0497-2627(1998)34:5<319:IERDOP>2.0.ZU;2-C
Abstract
Kinetic peculiarities of degradation of polycarbonates of various structure in dimethylformamide under the influence of the products of electrochemica l reduction of (C4H9)(4)NClO4 solution in dimethylformamide the background solution have been investigated. It has been shown that the process (which may be determined as an indirect electrochemical reductive degradation) pro ceeds via nucleophilic catalytic mechanism.