Jj. Blange et al., VIBRATIONAL-STATE DISTRIBUTION OF NA-2(+) IONS CREATED IN ULTRACOLD COLLISIONS, Physical review letters, 78(16), 1997, pp. 3089-3092
The vibrational distribution P(v) of Na-2(+) ions created in ultracold
collisions in a magneto-optical trap has been determined. Only two vi
brational states with v = 2 and 3 are populated and we find P(2) = 0.2
9 +/- 0.02 and P(3) = 0.71 +/- 0.02. The results provide conclusive ev
idence that the ionization mechanism is photoassociative autoionizatio
n, and not photoassociative photoionization, and will form a fundament
al test for the theoretical description of the process.