trans-Dichloro (hemiporphyrazinato)tin(IV)

Authors
Farris, PJ Jacobs, JT Okonczac, MP Durfee, WS Noll, BC
Citation
Pj. Farris et al., trans-Dichloro (hemiporphyrazinato)tin(IV), ACT CRYST C, 55, 1999, pp. 32-33
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
1
Pages
32 - 33
Database
ISI
SICI code
0108-2701(19990115)55:<32:T(>2.0.ZU;2-U
Abstract
trans-Dichloro(hemiporphyrazinato)tin(IV), [SnCl2(C26H14N8)], is a planar m acrocyclic complex with six-coordinate tin in an N-4 coordination site boun d to axial Cl ligands. The molecule has D-2h symmetry and is characterized by two short Sn-N(isoindole) bonds [2.041 (3)Angstrom] and two long Sn-N(py ridine) bonds [2.213 (4) Angstrom].