Bis(terpyridine)ruthenium(II) bis(hexafluorophosphate) diacetonitrile solvate

Authors
Lashgari, K Kritikos, M Norrestam, R Norrby, T
Citation
K. Lashgari et al., Bis(terpyridine)ruthenium(II) bis(hexafluorophosphate) diacetonitrile solvate, ACT CRYST C, 55, 1999, pp. 64-67
Citations number
21
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
1
Pages
64 - 67
Database
ISI
SICI code
0108-2701(19990115)55:<64:BBDS>2.0.ZU;2-F
Abstract
The crystal structure of the title compound, bis(2,2': 6',2''-terpyridine)r uthenium(II) bis(hexafluorophosphate) diacetonitrile solvate, with the comp osition [Ru(C15H11N3)(2)](PF6)(2). 2C(2)H(3)N is described. The pseudo-octa hedral Ru complex has a C-2 nu point symmetry, imposed by the geometry cons traints of the two identical tridentate ligands. The tetragonal unit cell, with its remarkably long c axis [49.306(3)Angstrom], contains two symmetry- independent formula units.