trans-Carbonylchlorobis(tri-p-tolylphosphine)rhodium(I)

Authors
Otto, S Mzamane, SN Roodt, A
Citation
S. Otto et al., trans-Carbonylchlorobis(tri-p-tolylphosphine)rhodium(I), ACT CRYST C, 55, 1999, pp. 67-69
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
1
Pages
67 - 69
Database
ISI
SICI code
0108-2701(19990115)55:<67:T>2.0.ZU;2-M
Abstract
The crystal structure of the square-planar title compound, [RhCl(C21H21P)(2 )(CO)], describes another of the Vaska-type complexes. It is isomorphous wi th selected Ir-I and even Pt-II structures. Important bond lengths include Rh-P1 2.3344(11), Rh-P2 2.3305 (11), Rh-C1 2.3581 (12), Rh-C1 1.798(5) and C1-01 1.139(6)Angstrom.