A typical perovskite La0.2Sr0.8Co0.2Fe0.8O3-delta (LSCF) membrane and a nov
el perovskite-related ZrO2-doped SrCo0.4Fe0.6O3-delta (SCFZ) membrane were
successfully prepared. The sintered membranes were characterized by an in-s
itu high-temperature X-ray diffraction, scanning electron microscopy and en
ergy dispersive spectroscopy. Oxygen permeabilities of the two dense membra
nes were measured in the temperature range of 923 to 1,173 K under a fixed
oxygen partial pressure gradient. The results of the oxygen permeation expe
riment and high-temperature X-ra diffraction in argon atmosphere indicate t
hat the perovskite-related SCFZ membrane has higher oxygen fluxes and is st
able than that of the LSCF membrane at elevated temperatures and reduced ox
ygen partial pressures.