N. Tomioka et K. Fujino, Akimotoite, (Mg,Fe)SiO3, a new silicate mineral of the ilmenite group in the Tenham chondrite, AM MINERAL, 84(3), 1999, pp. 267-271
Akimotoite, (Mg,Fe)SiO3, a new silicate mineral of the ilmenite group, was
found in the shock-metamorphosed Tenham chondrite. It occurs as aggregates
adjacent to clinoenstatite in fragments within shock-induced melt veins. Ch
emical analyses show the simplified formula to be (Mg0.79Fe0.21)SiO3, the s
ame as for clinoenstatite. Selected-area electron diffraction (SAED) patter
ns correspond to the synthetic (Mg,Fe)SiO3 ilmenite phase with space group
R (3) over bar. Lattice parameters derived from SAED patterns are a = 0.478
(5) nm, c = 1.36(1) nm and V = 0.269(8) nm(3) in the hexagonal setting. The
calculated density is 4.0(1) g/cm(3). Akimotoite in this occurrence is tho
ught to have been transformed from original orthoenstatite in a solid-state
reaction produced by a shock event. Peak pressure and temperature generate
d by shock events in Tenham are estimated to be 22 GPa <P-max < 26 GPa and
T-max >2000 degrees C, assuming that equilibrium crystallization of alumino
us majorite occurred in the melt veins. This new mineral was named after Sy
un-iti Akimoto.