Selective oxidation on chromia-pillared zirconium phosphate and phenylphosphonate

Authors
Xiao, JB Xu, JS Gao, Z
Citation
Jb. Xiao et al., Selective oxidation on chromia-pillared zirconium phosphate and phenylphosphonate, CATAL LETT, 57(1-2), 1999, pp. 37-42
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
CATALYSIS LETTERS
ISSN journal
1011372X → ACNP
Volume
57
Issue
1-2
Year of publication
1999
Pages
37 - 42
Database
ISI
SICI code
1011-372X(1999)57:1-2<37:SOOCZP>2.0.ZU;2-7
Abstract
Chromia-pillared zirconium phosphate and zirconium phenylphosphonate were p repared by an indirect intercalation method. The pillared materials have su rface area in the range of 316-462 m(2)/g and narrow pore size distribution s with greater than or equal to 70% mesoporosity. They are efficient cataly sts for selective oxidation of aromatics, alkanes, cycloalkanes, cycloalken es and alcohols using 30% H2O2 as the oxidant with catalytic activities muc h higher than CrAPOs and CrMCM-41.