'Inverse crown ether' complexes: extension to potassium through the synthesis of [{[(Me3Si)(2)N](4)K2Mg2(O-2)}(infinity)], a peroxo-centred macrocycle linked into infinite chains by intermolecular K center dot center dot center dot CH3(SiMe2) interactions

Authors
Kennedy, AR Mulvey, RE Raston, CL Roberts, BA Rowlings, RB
Citation
Ar. Kennedy et al., 'Inverse crown ether' complexes: extension to potassium through the synthesis of [{[(Me3Si)(2)N](4)K2Mg2(O-2)}(infinity)], a peroxo-centred macrocycle linked into infinite chains by intermolecular K center dot center dot center dot CH3(SiMe2) interactions, CHEM COMMUN, (4), 1999, pp. 353-354
Citations number
10
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
4
Year of publication
1999
Pages
353 - 354
Database
ISI
SICI code
1359-7345(19990221):4<353:'CECET>2.0.ZU;2-S
Abstract
The title compound represents the first potassium example of a novel class of amide-supported heterobimetallic macrocycle having a dicationic (N4K2Mg2 )(2+) octagonal ring framework surrounding a dianionic (O-2)(2-) core.