Transformation of fusicocca-2,10(14)-dien-8 beta-ol into fusicoccin J by the fusicoccin-producing fungus, Phomopsis (Fusicoccum) amygdali. Support for the intermediacy of fusicocca-2,10(14)-diene in the fusicoccin biosynthesis
N. Kato et al., Transformation of fusicocca-2,10(14)-dien-8 beta-ol into fusicoccin J by the fusicoccin-producing fungus, Phomopsis (Fusicoccum) amygdali. Support for the intermediacy of fusicocca-2,10(14)-diene in the fusicoccin biosynthesis, CHEM COMMUN, (4), 1999, pp. 367-368
(+)-Fusicocca-2,10(14)-diene, isolated recently by the authors, is most lik
ely a genuine hydrocarbon intermediate in the biosynthesis of fusicoccin, a
s its 8 beta-hydroxy derivative is smoothly and efficiently converted into
fusicoccin J by the fusicoccin-producing fungus, Phomopsis (Fusicoccum) amy
gdali F6.