The first transition metal cholesteryl-phosphine complexes

Authors
Soulivong, D Matt, D Ziessel, R
Citation
D. Soulivong et al., The first transition metal cholesteryl-phosphine complexes, CHEM COMMUN, (4), 1999, pp. 393-394
Citations number
14
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
4
Year of publication
1999
Pages
393 - 394
Database
ISI
SICI code
1359-7345(19990221):4<393:TFTMCC>2.0.ZU;2-N
Abstract
Novel optically pure cholesteryl-phosphine ligands (3 alpha-PPh(2)chol and 3 beta-PMe(2)chol) have been synthesized and were shown to form stable and highly soluble Pd(II) and Pt(II) complexes; as revealed by an X-ray analysi s the (chol)-P ... P(chol) fragment of the square planar trans-[PtI2(3 beta -PMe(2)chol)(2)] complex adopts a staggered arrangement (V-shape).