The mesophase behaviour of homologues N-(n-alkyl) pyridinium hydrogensulfat
es has been examined by thermal and optical studies. These cationic surfact
ants not only form thermotropic mesophases at relatively low temperatures (
about 100 degrees C), but also form lyotropic mesophases in the unconventio
nal solvent concentrated sulphuric acid. The sequences of lyotropic liquid
crystalline phases have been determined. (C) 1999 Elsevier Science B.V. All
rights reserved.