CRYSTAL-STRUCTURE OF [[(C2H4)(2)]]NC2H4NH2)(2)(AG(CN)(2))](N)CENTER-DOT N[AG(CN)(2)] - A CATIONIC 3-DIMENSIONAL FRAMEWORK BUILT OF HETERO-BRIDGED OCTAHEDRAL CD2-)( AND TETRAHEDRAL AG+ ACCOMMODATING ANIONIC GUEST [AG(CN)(2)]()
T. Soma et al., CRYSTAL-STRUCTURE OF [[(C2H4)(2)]]NC2H4NH2)(2)(AG(CN)(2))](N)CENTER-DOT N[AG(CN)(2)] - A CATIONIC 3-DIMENSIONAL FRAMEWORK BUILT OF HETERO-BRIDGED OCTAHEDRAL CD2-)( AND TETRAHEDRAL AG+ ACCOMMODATING ANIONIC GUEST [AG(CN)(2)](), Chemistry Letters, (4), 1997, pp. 319-320
In the title complex the N-(2-aminoethyl)piperazine and cyanide respec
tively bridge between octahedral Cd2+ and tetrahedral Ag+ to form a po
sitively-charged three-dimensional host framework accommodating [Ag(CN
)(2)](-) anion as the guest.