SYNTHESIS OF POLYCYCLIC COMPOUNDS BY THE REACTION OF CO-2(CO)(6) COMPLEXED 1-[O-(1-ALKYNYL)PHENYL]CYCLOPROPANOLS

Authors
IWASAWA N MATSUO T
Citation
N. Iwasawa et T. Matsuo, SYNTHESIS OF POLYCYCLIC COMPOUNDS BY THE REACTION OF CO-2(CO)(6) COMPLEXED 1-[O-(1-ALKYNYL)PHENYL]CYCLOPROPANOLS, Chemistry Letters, (4), 1997, pp. 341-342
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
4
Year of publication
1997
Pages
341 - 342
Database
ISI
SICI code
0366-7022(1997):4<341:SOPCBT>2.0.ZU;2-#
Abstract
1-[o-(1-Alkyinyl)phenyl]cyclopropanols are converted to 2,3-dihydro-1- naphthalenone derivatives by heating their hexacarbonyldicobalt comple xes in 2-propanol. Furthermore, a new type of isomerization-cyclizatio n reaction proceeds to give 3a,4-dihydro-3H-cyclopenta[a]inden-2-one d erivatives when the same reaction is carried out in the presence of DA BCO.