A 16-ELECTRON CYCLOBUTADIENE-BENZENE-1,2-DITHIOLATE COMPLEX OF PALLADIUM(II) BEARING - A 2-LEGGED PIANO-STOOL GEOMETRY - (ETA(4)-C4ME2(BU-T)(2))PD(1,2-S2C6H4)

Authors
MASHIMA K KANEKO S TANI K
Citation
K. Mashima et al., A 16-ELECTRON CYCLOBUTADIENE-BENZENE-1,2-DITHIOLATE COMPLEX OF PALLADIUM(II) BEARING - A 2-LEGGED PIANO-STOOL GEOMETRY - (ETA(4)-C4ME2(BU-T)(2))PD(1,2-S2C6H4), Chemistry Letters, (4), 1997, pp. 347-348
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
4
Year of publication
1997
Pages
347 - 348
Database
ISI
SICI code
0366-7022(1997):4<347:A1CCOP>2.0.ZU;2-I
Abstract
A 16-electron cyclobutadiene-palladium(II)-thiolate complex (eta(4)-C4 Me2(Bu-t)(2))Pd(S2C6H4) (2: S2C6H4 = 1,2-benzenedithiolate) is prepare d by treatment of [(eta(4)-C4Me2(Bu-t)(2))PdCl2](2) (1) with disodium 1,2-benzenedithiolate, and its monomeric two-legged piano-stool struct ure was characterized by X-ray analysis as well as its LMCT band cause d by donation of the filled S(p pi) electrons to the empty Pd(d pi) o rbital.