Development of a Modified Bromley's Methodology for the estimation of ionic media effects on solution equilibria Part 4. The chemical model of Fe(III) with the halide ligands in aqueous solution at 25 degrees C

Authors
Belaustegi, Y Olazabal, MA Madariaga, JM
Citation
Y. Belaustegi et al., Development of a Modified Bromley's Methodology for the estimation of ionic media effects on solution equilibria Part 4. The chemical model of Fe(III) with the halide ligands in aqueous solution at 25 degrees C, FLU PH EQUI, 155(1), 1999, pp. 21-31
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
FLUID PHASE EQUILIBRIA
ISSN journal
03783812 → ACNP
Volume
155
Issue
1
Year of publication
1999
Pages
21 - 31
Database
ISI
SICI code
0378-3812(19990205)155:1<21:DOAMBM>2.0.ZU;2-D
Abstract
The Modified Bromley's Methodology (MBM) has been used to construct the bas ic chemical model between Fe(III) and OH- and the halide ligands Cl-, Br- a nd F- in NaClO4 medium at 25 degrees C, obtaining the thermodynamic constan ts and the corresponding interaction parameters for each equilibrium. This basic model has been extended to KNO3, HCl, and KCl media obtaining the cor responding interaction parameters. The applicability of the model is also d iscussed. (C) 1999 Elsevier Science B.V. All rights reserved.