A new biflavanone (1) named (+)-GB-1b was isolated together with five known
biflavonoids from the stems of Garcinia kola Heckel (Guttiferae) collected
in Nigeria. The structure was characterized by analyses of the spectral da
ta. The stereostructures of (-)-GB-1a, (+)-GB-1b and (-)-GB-2a are also dis
cussed on the basis of chemical and spectroscopic evidence. Furthermore, 3,
8 "-biflavanones were successfully converted to 3,6 "-biflavanone under the
rmal conditions.